Petroleum Science >2012,??Issue 4:??544-550 DOI: https://doi.org/10.1007/s12182-012-0241-6
Quasi-solid state synthesis of EU-1 zeolite andits catalytic properties for the isomerization ofC8 aromatics Open?Access
文章信息
Chemical Engineering Department, Taiyuan University of Technology, Taiyuan, Shanxi 030024, China;1 Chemical Engineering Department, Taiyuan University of Technology, Taiyuan, Shanxi 030024, China;2 Petrochemical Research Institute, CNPC, Beijing 100083, China;3 New Energy Research Institute, CNOOC New Energy Investment Co., Ltd., Beijing 100016, China 4 China University of Petroleum, Beijing102249, China;1 Chemical Engineering Department, Taiyuan University of Technology, Taiyuan, Shanxi 030024, China 4 China University of Petroleum, Beijing102249, China
文章摘要
assembled to catalyst for the C8 aromatics isomerization process. The catalytic properties were tuned
through careful modification of the acidity of EU-1 zeolites and metal-doping of the catalyst. It was
shown that EU-1 was an excellent candidate for the C8 aromatics isomerization process due to its unique
structure. In addition, steam treatment of EU-1 at 450-500 °C could optimize the acidic properties of
the catalyst, hence enhance its catalytic performance. The effect of the amount of Pt on ethylbenzene
conversion was studied and the optimum amount was determined to be about 0.3-0.4 wt%. It was
confirmed that EU-1 zeolite prepared via a quasi-solid state approach and then dealuminated by steam
treatment had better activity and selectivity than conventional mordenite (MOR) zeolite and could be an
excellent candidate for C8 aromatics isomerization.
關鍵詞
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EU-1 zeolite, acidity, metallic function, isomerization