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Petroleum Science >2017,??Issue 3:??507-519 DOI: https://doi.org/10.1007/s12182-017-0176-z

Impact of formation water on the generation of H₂S in condensate reservoirs: a case study from the deep Ordovician in the Tazhong Uplift of the Tarim Basin, NW China Open?Access

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作者：Jin Su, Yu Wang, Xiao-Mei Wang, Kun He, Hai-Jun Yang, Hui-Tong Wang, Hua-Jian Wang, Bin Zhang, Ling Huang, Na Weng, Li-Na Bi and Zhi-Hua Xiao

作者單位：

Key Laboratory of Petroleum Geochemistry, CNPC, Beijing 100083, China; State Key Laboratory for Enhancing Oil Recovery, Research Institute of Petroleum Exploration and Development, PetroChina, Beijing 100083, China,Key Laboratory of Petroleum Geochemistry, CNPC, Beijing 100083, China; State Key Laboratory for Enhancing Oil Recovery, Research Institute of Petroleum Exploration and Development, PetroChina, Beijing 100083, China,Key Laboratory of Petroleum Geochemistry, CNPC, Beijing 100083, China; State Key Laboratory for Enhancing Oil Recovery, Research Institute of Petroleum Exploration and Development, PetroChina, Beijing 100083, China,Key Laboratory of Petroleum Geochemistry, CNPC, Beijing 100083, China; State Key Laboratory for Enhancing Oil Recovery, Research Institute of Petroleum Exploration and Development, PetroChina, Beijing 100083, China,Research Institute of Tarim Oilfield Company, PetroChina, Korla 841000, Xinjiang, China,Key Laboratory of Petroleum Geochemistry, CNPC, Beijing 100083, China; State Key Laboratory for Enhancing Oil Recovery, Research Institute of Petroleum Exploration and Development, PetroChina, Beijing 100083, China,Key Laboratory of Petroleum Geochemistry, CNPC, Beijing 100083, China; State Key Laboratory for Enhancing Oil Recovery, Research Institute of Petroleum Exploration and Development, PetroChina, Beijing 100083, China,Key Laboratory of Petroleum Geochemistry, CNPC, Beijing 100083, China; State Key Laboratory for Enhancing Oil Recovery, Research Institute of Petroleum Exploration and Development, PetroChina, Beijing 100083, China,Key Laboratory of Petroleum Geochemistry, CNPC, Beijing 100083, China; State Key Laboratory for Enhancing Oil Recovery, Research Institute of Petroleum Exploration and Development, PetroChina, Beijing 100083, China,Key Laboratory of Petroleum Geochemistry, CNPC, Beijing 100083, China; State Key Laboratory for Enhancing Oil Recovery, Research Institute of Petroleum Exploration and Development, PetroChina, Beijing 100083, China,Key Laboratory of Petroleum Geochemistry, CNPC, Beijing 100083, China; State Key Laboratory for Enhancing Oil Recovery, Research Institute of Petroleum Exploration and Development, PetroChina, Beijing 100083, China and PetroChina Coalbed Methane Company Limited, Beijing 100028, China

投稿時間：2016-09-25

引用方式：Su, J., Wang, Y., Wang, XM. et al. Pet. Sci. (2017) 14: 507. https://doi.org/10.1007/s12182-017-0176-z

文章摘要

A number of condensate reservoirs with high concentrations of H₂S have been discovered in the deep dolomite reservoirs of the lower Ordovician Yingshan Formation (O₁y) in the Tazhong Uplift, where the formation water has a high pH value. In the O₁y reservoir, the concentrations of Mg²⁺ and SO₄^2- in the formation water are higher than those in the upper Ordovician formation. The concentration of H₂S in the condensate reservoirs and the concentration of Mg²⁺ in the formation water correlate well in the O₁y reservoirs of the Tazhong Uplift, which indicates a presumed thermochemical sulfate reduction (TSR) origin of H₂S according to the oxidation theory of contact ion-pairs (CIPs). Besides, the pH values of the formation water are positively correlated with the concentration of H₂S in the condensate reservoirs, which may indicate that high pH might be another factor to promote and maintain TSR. Oil–source correlation of biomarkers in the sulfuretted condensates indicates the Cambrian source rocks could be the origin of condensates. The formation water in the condensate reservoirs of O₁y is similar to that in the Cambrian; therefore, the TSR of sulfate-CIPs likely occurred in the Cambrian. High H₂S-bearing condensates are mainly located near the No. 1 Fault and NE-SW strikeslip faults, which are the major migration pathway of deep fluids in the Tazhong Uplift. The redox between sulfate- CIPs and hydrocarbons is the generation mechanism of H₂S in the deep dolomite condensate reservoirs of the Tazhong Uplift. This finding should be helpful to predict the fluid properties of deep dolomite reservoirs.

關鍵詞

Formation water, Sulfate-CIPs, TSR, Condensates, Dolomite reservoir, Tarim basin

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