Petroleum Science >2023,??Issue4:??- DOI: https://doi.org/10.1016/j.petsci.2023.03.005
A mini review on oxidative dehydrogenation of propane over boron nitride catalysts Open?Access
文章信息
作者：Zhu Fu, De-Zheng Li, Li-Dai Zhou, Yu-Ming Li, Jia-Wen Guo, Yu-Qiao Li, Hui-Min Liu, Qi-Jian Zhang
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引用方式：Zhu Fu, De-Zheng Li, Li-Dai Zhou, Yu-Ming Li, Jia-Wen Guo, Yu-Qiao Li, Hui-Min Liu, Qi-Jian Zhang, A mini review on oxidative dehydrogenation of propane over boron nitride catalysts, Petroleum Science, Volume 20, Issue 4, 2023, Pages 2488-2498, https://doi.org/10.1016/j.petsci.2023.03.005.
文章摘要
Abstract: Oxidative dehydrogenation of propane is an attractive route for the synthesis of propylene due to its favorable thermodynamic and kinetic characteristics, however, it is challenging to realize high selectivity towards propylene. Recently, it has been discovered that boron nitride (BN) is a promising catalyst that affords superior selectivity towards propylene in oxidative dehydrogenation of propane. Summarizing the progress and unravelling the reaction mechanism of BN in oxidative dehydrogenation of propane are of great significance for the rational design of efficient catalysts in the future. Herein, in this review, the underlying reaction mechanisms of oxidative dehydrogenation of propane over BN are extracted; the developed BN catalysts are classified into pristine BN, functionalized BN, supported BN and others, and the applications of each category of BN catalysts in oxidative dehydrogenation of propane are summarized; the challenges and opportunities on oxidative dehydrogenation of propane over BN are pointed out, aiming to inspire more studies and advance this research field.
關鍵詞
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Keywords: Oxidative dehydrogenation of propane; Boron nitride; Propylene; Reaction mechanism